Applications of "planar-chiral" heterocycles in asymmetric catalysis
نویسندگان
چکیده
منابع مشابه
Chiral allene-containing phosphines in asymmetric catalysis.
We demonstrate that allenes, chiral 1,2-dienes, appended with basic functionality can serve as ligands for transition metals. We describe an allene-containing bisphosphine that, when coordinated to Rh(I), promotes the asymmetric addition of arylboronic acids to α-keto esters with high enantioselectivity. Solution and solid-state structural analysis reveals that one olefin of the allene can coor...
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ژورنال
عنوان ژورنال: Pure and Applied Chemistry
سال: 2001
ISSN: 1365-3075,0033-4545
DOI: 10.1351/pac200173071113